(Polyhalophenyl)silver(I) complexes as arylating agents: Crystal structure of [(µ-2,4,6-C6F3H2)(AuPPh3)2]ClO4

  1. Usón, R. 2
  2. Laguna, A. 2
  3. Fernández, E.J. 1
  4. Mendia, A. 1
  5. Jones, P.G. 3
  1. 1 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  3. 3 University of Göttingen
    info

    University of Göttingen

    Gotinga, Alemania

    ROR https://ror.org/01y9bpm73

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Journal:
Journal of Organometallic Chemistry

ISSN: 0022-328X

Year of publication: 1988

Volume: 350

Issue: 1

Pages: 129-138

Type: Article

SCOPUS: 2-s2.0-0012625229 WoS: WOS:A1988P567000014 GOOGLE SCHOLAR

More publications in: Journal of Organometallic Chemistry

Abstract

The arylsilver derivatives AgR (R = C6F5, 2,4,6-C6F3H2 or C6Cl5) react with chlorogold(I) precursors [AuCl(tht), AuCl(PPh3), ClAu(dppm)AuCl (tht = tetrahydrothiophene, dppm = bis(diphenylphosphino)methane], to give the corresponding arylgold complexes in good yield. With gold precursors in higher oxidation state, AgC6Cl5 either causes reduction to gold(I) or gives no reaction, whereas AgC6F5 and AgC6F3H2 lead to gold(II) complexes (R2Au(dppm)AuR2) or gold (III) complexes [Au(C6F3H2)(C6F5)2(PPh3); Au(C6F3H2)2(C6F5)(tht); Au(C6F5)3(tht); Au(C6F3H2)3(tht)]. © 1988.