Complejos metalosupramoleculares de Cu(I), Ag(I), Au(I), Pd(II) y Pt(II)síntesis, caracterización estructural y propiedades biológicas
- González Barcia, Luis MIguel
- Manuel R. Bermejo Patiño Directeur/trice
- Ana María González Noya Co-directeur/trice
- Rosa Pedrido Castiñeiras Co-directeur/trice
Université de défendre: Universidade de Santiago de Compostela
Fecha de defensa: 20 décembre 2019
- Javier García Tojal President
- M. Angeles Sanchez Gonzalez Secrétaire
- M. Emilia Bertolo Pardo Rapporteur
Type: Thèses
Résumé
In this thesis, metallosupramolecular compounds of Cu(I), Ag(I), Au(I), Pd(II) and Pt(II) have been developed from functionalized ligands with phosphines (Schiff bases, thiosemicarbazones and semicarbazones) which have allowed us to obtain valuable information for the comprehension of self-assembly processes in that kind of systems. In particular, the desulfurization process of a double cluster helicate derived from Ag(I) and thiosemicarbazone has been studied in detail. The great relevance of some of these metal ions at the biological level has allowed a preliminary evaluation of the potential complexes applications as possible metallodrugs.